Material Safety Data Sheet
    Calcium Sulfate
ACC# 04110
  
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Section 1 - Chemical Product and Company Identification | 
  
MSDS Name: Calcium Sulfate
Catalog Numbers:
     S799481, S93166, C-140
Synonyms:
     Sulfuric acid calcium salt, gypsum, mineral white, alabaster, satin
     spar, selenite
Company Identification:
 
 
 
 
 
 
 
Fisher Scientific
 
 
 
 
 
 
 
1 Reagent Lane
 
 
 
 
 
 
 
Fair Lawn, NJ  07410
For information, call:  201-796-7100
Emergency Number:       201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
  
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Section 2 - Composition, Information on Ingredients
 | 
  | CAS# | 
    Chemical Name | 
    Percent | 
    EINECS/ELINCS | 
|    7778-18-9 | 
Calcium sulfate | 
   100    | 231-900-3 | 
  
    | 
Section 3 - Hazards Identification
 | 
EMERGENCY OVERVIEW
Appearance: white with a blue, gray or red hue solid.
 Caution! May cause eye, skin, and respiratory
tract irritation.
Target Organs: None.
Potential Health Effects
     
Eye:
          Causes eye irritation.  May cause conjunctivitis.
     
Skin:
          Causes skin irritation. Chronic exposure has been linked with
          rhinitis (inflammation of the mucous membrane of the nose),
          nosebleeds, laryngitis, pharyngitis, lung membrane effects, and an
          impaired sense of smell and taste.
     
Ingestion:
          Ingestion of large amounts may cause gastrointestinal irritation.
          May cause mechanical obstruction of the digestive
     
Inhalation:
          Dust is irritating to the respiratory tract.
     
Chronic:
          Chronic exposure has been linked with rhinitis (inflammation of the
          mucous membrane of the nose), nosebleeds, laryngitis, pharyngitis,
          lung membrane effects, and an impaired sense of smell and taste.
  
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Section 4 - First Aid Measures
 | 
     
Eyes:
          Flush eyes with plenty of water for at least 15 minutes, occasionally
          lifting the upper and lower eyelids. Get medical aid.
     
Skin:
          Flush skin with plenty of water for at least 15 minutes while
          removing contaminated clothing and shoes. Get medical aid if
          irritation develops or persists.
     
Ingestion:
          If victim is conscious and alert, give 2-4 cupfuls of milk or water.
          Get medical aid.
     
Inhalation:
          Remove from exposure and move to fresh air immediately. Get medical
          aid if cough or other symptoms appear.
     
Notes to Physician:
          Treat symptomatically and supportively.
  
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Section 5 - Fire Fighting Measures
 | 
     
General Information:
          As in any fire, wear a self-contained breathing apparatus in
          pressure-demand, MSHA/NIOSH (approved or equivalent), and full
          protective gear.
     
Extinguishing Media:
          Substance is noncombustible; use agent most appropriate to
          extinguish surrounding fire.
Flash Point: Not applicable.
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
                  Upper: Not available.
     
NFPA Rating:
(estimated) Health: 1; Flammability: 0; Instability: 0
  
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Section 6 - Accidental Release Measures
 | 
     
General Information: Use proper personal protective equipment as indicated
                          in Section 8.
     
Spills/Leaks:
          Vacuum or sweep up material and place into a suitable disposal
          container.
  
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Section 7 - Handling and Storage
 | 
     
Handling:
          Use with adequate ventilation. Minimize dust generation and
          accumulation. Avoid contact with skin and eyes. Avoid ingestion and
          inhalation.
     
Storage:
          Store in a tightly closed container. Store in a cool, dry,
          well-ventilated area away from incompatible substances.
  
    | 
Section 8 - Exposure Controls, Personal Protection
 | 
     
Engineering Controls:
          Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
  | Chemical Name | 
    ACGIH | 
    NIOSH | 
    OSHA - Final PELs | 
| Calcium sulfate
 | 
10 mg/m3 TWA (particulate matter containing no asbestos and < 1% crystalline sil ica)
 | 
10 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable dust)
 | 
15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction)
 | 
     
OSHA Vacated PELs:
          Calcium sulfate:
          15 mg/m3 TWA; 5 mg/m3 TWA (respirable fraction)
     
Personal Protective Equipment
                 
Eyes:
                       Wear appropriate protective eyeglasses or chemical
                       safety goggles as described by OSHA's eye and face
                       protection regulations in 29 CFR 1910.133 or European
                       Standard EN166.
                 
Skin:
                       Wear appropriate protective gloves to prevent skin
                       exposure.
             
Clothing:
                       Wear appropriate protective clothing to minimize
                       contact with skin.
          
Respirators:
                       Follow the OSHA respirator regulations found in 29
                       CFR 1910.134 or European Standard EN 149. Use a
                       NIOSH/MSHA or European Standard EN 149 approved
                       respirator if exposure limits are exceeded or if
                       irritation or other symptoms are experienced.
  
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Section 9 - Physical and Chemical Properties
 | 
Physical State:  Solid
Appearance:      white with a blue, gray or red hue
Odor:            Odorless.
pH:              Not available.
Vapor Pressure:  Not applicable.
Vapor Density:   Not available.
Evaporation Rate:Not applicable.
Viscosity:       Not available.
Boiling Point:   2179 deg F
Freezing/Melting Point:2642 deg F
Decomposition Temperature:Not available.
Solubility:      0.2% in water.
Specific Gravity/Density:2.964
Molecular Formula:CaSO4
Molecular Weight:136.1376
  
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Section 10 - Stability and Reactivity
 | 
     
Chemical Stability:
          Stable under normal temperatures and pressures.
     
Conditions to Avoid:
          Incompatible materials, moisture.
     
Incompatibilities with Other Materials:
          Calcium sulfate is incompatible with aluminum and diazonethane. At
          high temperatures, mixtures of calcium sulfate and phosphorus
          ignites.
     
Hazardous Decomposition Products:
          Oxides of sulfur.
     
Hazardous Polymerization: Has not been reported.
  
    | 
Section 11 - Toxicological Information
 | 
     
RTECS#:
     
CAS# 7778-18-9:
WS6920000
     
LD50/LC50:
          Not available.
     
Carcinogenicity:
       CAS#    7778-18-9:
          Not listed by ACGIH, IARC, NTP, or CA Prop 65.
     
Epidemiology:
          No data available.
     
Teratogenicity:
          No data available.
     
Reproductive Effects:
          No data available.
     
Mutagenicity:
          No data available.
     
Neurotoxicity:
          No data available.
     
Other Studies:
  
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Section 12 - Ecological Information
 | 
          No information available.
  
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Section 13 - Disposal Considerations
 | 
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
  
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Section 14 - Transport Information
 | 
  |        | 
    US DOT | 
    Canada TDG | 
| Shipping Name: | 
Not regulated as a hazardous material | 
No information available. | 
| Hazard Class: | 
 | 
 | 
| UN Number: | 
 | 
 | 
| Packing Group: | 
 | 
 | 
  
    | 
Section 15 - Regulatory Information
 | 
 US FEDERAL
     
TSCA
     CAS# 7778-18-9 is listed on the TSCA inventory.
        
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
        
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
        
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
        
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
        
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
        
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
        
Section 313
     No chemicals are reportable under Section 313.
     
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
     
Clean Water Act:
     None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
     None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
     
OSHA:
     None of the chemicals in this product
are considered highly hazardous by OSHA.
 
STATE
          CAS#    7778-18-9 can be found on the
     following state right to know lists: Pennsylvania, Minnesota,
     Massachusetts.
 
California Prop 65
     
California No Significant Risk Level:
     None of the chemicals in this product are listed.
 
European/International Regulations
     European Labeling in Accordance with EC Directives
          Hazard Symbols:
      Not available.
          
Risk Phrases:
          
Safety Phrases:
   
WGK (Water Danger/Protection)
     CAS# 7778-18-9: 0
   Canada - DSL/NDSL
     CAS# 7778-18-9 is listed on Canada's DSL List.
   Canada - WHMIS
     WHMIS: Not available.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
   Canadian Ingredient Disclosure List
  
    | 
Section 16 - Additional Information
 | 
     MSDS Creation Date: 12/12/1997  
Revision #3 Date: 10/03/2005
     The information above is believed to be accurate and represents the best
     information currently available to us. However, we make no warranty of
     merchantability or any other warranty, express or implied, with respect to
     such information, and we assume no liability resulting from its use. Users
     should make their own investigations to determine the suitability of the
     information for their particular purposes. In no event shall Fisher be liable
     for any claims, losses, or damages of any third party or for lost profits
     or any special, indirect, incidental, consequential or exemplary
     damages, howsoever arising, even if Fisher has been advised of
     the possibility of such damages.